Organic Electrosyntheses. X. Preparation of N-Benzylidene-tert-butylamine N-oxide.
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چکیده
منابع مشابه
N-[2-(2-Methoxyphenyl)benzylidene]-tert-butylamine N-oxide
In the mol-ecule of the title compound, C(18)H(21)NO(2), the two benzene rings are oriented at a dihedral angle of 58.19 (3)°. Intra-molecular C-H⋯O hydrogen bonds result in the formation of one six- and one five-membered ring, which adopt twist and envelope conformations, respectively. In the crystal structure, C-H⋯O hydrogen bonds link the mol-ecules.
متن کاملATTEMPTED PREPARATION OF N-SUBSTITUTED DIPHENYLCYCLOPROPENEIMINE N-OXIDE
The reaction of diphenylcyclopropenone with several N-substituted hydroxylamine and primary amines are investigated. Most of these reactions led to ring opened or ring enlarged products, instead of the desired N-Oxide or imine. The reaction of cyclopropeneimine with peracid-another possible route to N-substituted cyclopropeneimine N-Oxide is studied. Most of the unexpected products are ide...
متن کاملTrichlorido(N,N′-di-tert-butylbenzamidinato-κ2 N,N′)silicon
In the title mol-ecule, C(15)H(23)Cl(3)N(2)Si, the Si atom is penta-coordinated by two N atoms [Si-N = 1.780 (3) and 1.931 (3) Å] from the benzamidinate ligand and three chloride anions [Si-Cl = 2.0711 (14)-2.1449 (14) Å] in a distorted trigonal-bipyramidal geometry.
متن کاملN,N-Bis(2-pyridylmethyl)-tert-butylamine
In the title compound, C(16)H(21)N(3), the dihedral angle between the two pyridine rings is 88.11 (9)°. In the crystal, mol-ecules are linked through inter-molecular C-H⋯π inter-actions, forming a layer expanding parallel to the (10) plane.
متن کاملN-Phenyl-tert-butanesulfinamide
In the racemic title compound, C(10)H(15)NOS, the packing exhibits centrosymmetric pairs of mol-ecules linked by N-H⋯O=S hydrogen bonds in a head-to-tail fashion. The N-C(ar-yl) bond [1.4083 (12) Å] is considerably shorter than the N-C(alk-yl) bonds typically found in N-alkyl-alkanesulfinamides (1.470-1.530 Å).
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1977
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.31b-0733